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Diammonium phosphate

Also known as: DAP, (NH₄)₂HPO₄

Diammonium phosphate is the most widely traded phosphorus fertilizer in the world, supplying high concentrations of both phosphorus and nitrogen, with a locally alkaline reaction around the dissolving granule that briefly raises pH near the fertilizer band.

Dated referenceLast reviewed: 2026-07-12Updated: 2026-07-12
Illustrative diagram · AgricultureID (original)

Diammonium phosphate (DAP), (NH₄)₂HPO₄, is manufactured by fully neutralising phosphoric acid with ammonia. It typically analyses around 18% nitrogen and 46% phosphorus (as P₂O₅), making it one of the highest-analysis solid fertilizers in global trade.

Unlike monoammonium phosphate, DAP creates a temporary zone of elevated pH around the dissolving granule as ammonium is released, before nitrification lowers the pH again. It is used across a very wide range of crops and cropping systems worldwide.

Composition and analysis

DAP is produced by fully neutralising phosphoric acid with ammonia gas, yielding a granular salt with a guaranteed analysis of roughly 18% nitrogen and 46% phosphorus. It is one of the world’s most widely produced and traded fertilizers.

Chemical formula
(NH₄)₂HPO₄
Nitrogen content
About 18% total nitrogen, as ammonium
Phosphorus content
About 46% P₂O₅, highly water-soluble
Granule reaction
Locally alkaline as the granule dissolves, then neutralises

Nutrients supplied

DAP supplies phosphorus as its dominant nutrient in a highly water-soluble form, together with a substantial secondary contribution of nitrogen as ammonium, both released together as the granule dissolves.

  • Phosphorus is supplied at high concentration and full water solubility
  • Nitrogen is supplied as ammonium and nitrifies over time
  • No potassium or micronutrients are supplied

Use and benefits

DAP is used across cereal, oilseed, and many other cropping systems worldwide, often as a base phosphorus source in blended or compound fertilizer programs, and in some systems as a starter fertilizer.

  • High analysis reduces bulk and handling cost per unit of nutrient
  • Full water solubility supports rapid nutrient release once applied
  • Common base material for compound NPK fertilizers

Application principles

Because phosphorus moves little through most soils, DAP is generally most effective when placed where developing roots can access it. Some care is taken to avoid placing DAP in direct contact with germinating seed at high rates, since the temporary alkaline reaction and ammonia release near the granule can affect sensitive seedlings.

Environmental considerations

As with other phosphate fertilizers, the principal environmental concern is phosphorus movement to surface water, mainly through erosion and runoff of phosphorus-enriched soil, which can contribute to eutrophication.

Relationships

Evidence-backed connections in the knowledge graph.

Scope & limitations

Geographic scope: Global overview of diammonium phosphate as a major traded phosphorus fertilizer. Blending practices and use vary by cropping system and region.

Climate context: Cold soils slow phosphorus diffusion to roots, which can increase the practical importance of placement in early-season applications in cool climates.

  • This entry describes composition and general behaviour; it is not a phosphorus rate recommendation.
  • Phosphorus availability depends strongly on soil pH, texture, and phosphorus-fixing capacity, which are not detailed for specific soils here.
  • Seed-safety considerations for in-furrow or seed-placed DAP vary by crop and rate and should follow local agronomic guidance.

Sources

This article draws on the following authoritative sources. See our sources & methodology for how they are selected.

  1. [1]FAO — Food and Agriculture Organization (opens in a new tab)

    Food and Agriculture Organization of the United Nations (FAO)

    Authoritative

    Cited for: Global phosphorus fertilizer production and use

    Type:
    Intergovernmental organization
    Jurisdiction:
    Global
    Accessed:
    2026-07-12
  2. [2]IFA — International Fertilizer Association (opens in a new tab)

    International Fertilizer Association (IFA)

    Moderate

    Cited for: Diammonium phosphate product characteristics

    Type:
    Standards body
    Jurisdiction:
    Global
    Accessed:
    2026-07-12
  3. [3]USDA NRCS — Natural Resources Conservation Service (opens in a new tab)

    USDA Natural Resources Conservation Service (NRCS)

    Authoritative

    Cited for: Phosphorus behaviour and loss pathways in soil

    Type:
    Government agency
    Jurisdiction:
    United States
    Accessed:
    2026-07-12
  4. [4]AHDB — Agriculture and Horticulture Development Board (opens in a new tab)

    Agriculture and Horticulture Development Board (AHDB)

    High

    Cited for: Phosphorus management context

    Type:
    Government agency
    Jurisdiction:
    United Kingdom
    Accessed:
    2026-07-12