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Monoammonium phosphate

Also known as: MAP, NH₄H₂PO₄

Monoammonium phosphate is a high-analysis, water-soluble phosphorus fertilizer that also supplies a modest amount of nitrogen, widely used as a starter and blending material because of its low salt index and slightly acidifying reaction near the granule.

Dated referenceLast reviewed: 2026-07-12Updated: 2026-07-12
Illustrative diagram · AgricultureID (original)

Monoammonium phosphate (MAP), NH₄H₂PO₄, is manufactured by reacting phosphoric acid with ammonia in proportions that leave the product acidic. Its typical analysis is about 11% nitrogen and 52% phosphorus (expressed as P₂O₅), making it one of the most concentrated phosphorus fertilizers in common use.

Because MAP dissolves readily and creates a localised zone of low pH around the dissolving granule, it is a common choice for starter fertilizer applications near the seed or root zone at planting, and it is also blended with other materials to build compound NPK products.

Composition and analysis

MAP is produced by partially neutralising phosphoric acid with ammonia, yielding an acidic salt with a guaranteed analysis of roughly 11% nitrogen and 52% phosphorus (as P₂O₅). It contains no potassium.

Chemical formula
NH₄H₂PO₄
Nitrogen content
About 11% total nitrogen, as ammonium
Phosphorus content
About 52% P₂O₅, highly water-soluble
Granule reaction
Acidic zone forms around the dissolving granule

Nutrients supplied

MAP supplies phosphorus, its dominant nutrient, in a highly water-soluble form, along with a smaller amount of nitrogen as ammonium. The phosphorus and nitrogen are released together as the granule dissolves in soil moisture.

  • Phosphorus is the primary nutrient, at high concentration and full water solubility
  • Nitrogen is supplied as ammonium, a secondary but useful contribution
  • No potassium or micronutrients are supplied

Use and benefits

MAP is widely used as a starter fertilizer placed near the seed or root zone at planting, where early phosphorus availability supports root establishment, and as a base material for compound fertilizer blends and soluble fertigation programs.

  • High phosphorus concentration reduces bulk and handling cost per unit of nutrient
  • Complete water solubility suits banded starter placement and fertigation
  • Common building block for NPK blends and liquid fertilizer formulations

Application principles

Phosphorus from MAP, as with other phosphate fertilizers, is most effective when placed close to developing roots, since phosphorus moves little in most soils. General practice accounts for soil phosphorus status and pH, both of which strongly affect phosphorus availability.

Environmental considerations

Phosphorus lost from fields, whether dissolved or attached to eroded soil particles, can contribute to the eutrophication of surface waters. Because phosphorus binds strongly to many soils, surface runoff and erosion, rather than leaching, are usually the main loss pathways of concern.

Relationships

Evidence-backed connections in the knowledge graph.

Scope & limitations

Geographic scope: Global overview of monoammonium phosphate as a phosphorus fertilizer. Suitability for starter placement and blending practices vary by cropping system and region.

Climate context: Cold, wet soils in early spring can restrict root growth and phosphorus diffusion, increasing the practical value of concentrated, soluble phosphorus placed near the root zone in some systems.

  • This entry describes composition and general behaviour; it is not a phosphorus rate recommendation.
  • Phosphorus availability from MAP depends strongly on soil pH, texture, and phosphorus-fixing capacity, which are not detailed for specific soils here.
  • Starter-placement benefits are context-dependent and should be evaluated against local trial data and soil test results.

Sources

This article draws on the following authoritative sources. See our sources & methodology for how they are selected.

  1. [1]FAO — Food and Agriculture Organization (opens in a new tab)

    Food and Agriculture Organization of the United Nations (FAO)

    Authoritative

    Cited for: Phosphorus fertilizer sources and plant availability

    Type:
    Intergovernmental organization
    Jurisdiction:
    Global
    Accessed:
    2026-07-12
  2. [2]IFA — International Fertilizer Association (opens in a new tab)

    International Fertilizer Association (IFA)

    Moderate

    Cited for: Monoammonium phosphate product characteristics

    Type:
    Standards body
    Jurisdiction:
    Global
    Accessed:
    2026-07-12
  3. [3]USDA NRCS — Natural Resources Conservation Service (opens in a new tab)

    USDA Natural Resources Conservation Service (NRCS)

    Authoritative

    Cited for: Phosphorus behaviour and loss pathways in soil

    Type:
    Government agency
    Jurisdiction:
    United States
    Accessed:
    2026-07-12
  4. [4]AHDB — Agriculture and Horticulture Development Board (opens in a new tab)

    Agriculture and Horticulture Development Board (AHDB)

    High

    Cited for: Phosphorus management and starter fertilizer context

    Type:
    Government agency
    Jurisdiction:
    United Kingdom
    Accessed:
    2026-07-12