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Muriate of potash

Also known as: MOP, Potassium chloride, KCl

Muriate of potash is the most widely used potassium fertilizer worldwide, supplying potassium as a highly soluble chloride salt mined from underground potash deposits, favoured for its low cost per unit of potassium but used cautiously on chloride-sensitive crops.

Dated referenceLast reviewed: 2026-07-12Updated: 2026-07-12
Illustrative diagram · AgricultureID (original)

Muriate of potash (MOP), potassium chloride (KCl), is refined from potash ore mined from ancient evaporite deposits. Typical products analyse around 60% potassium, expressed as K₂O, making it the highest-analysis potassium fertilizer in common commercial use.

MOP supplies both potassium and chloride, two essential plant nutrients, in a single soluble salt. While chloride is required by plants only in small amounts, some crops are sensitive to higher chloride levels, which affects where MOP is favoured relative to potassium sulfate.

Composition and analysis

MOP is refined from mined potash ore (sylvinite) through processes such as flotation or dissolution-recrystallisation, yielding potassium chloride at a typical guaranteed analysis of about 60% K₂O.

Chemical formula
KCl
Potassium content
About 60% K₂O
Chloride content
About 45–47%, supplied alongside potassium
Source
Mined from underground evaporite (potash) deposits

Nutrients supplied

MOP supplies potassium, an essential macronutrient involved in water regulation, enzyme activation, and overall plant vigour, together with chloride, a nutrient required in much smaller amounts but present in relatively high proportion in this fertilizer.

  • Potassium is highly water-soluble and readily taken up by roots
  • Chloride accompanies potassium in every unit applied
  • No nitrogen, phosphorus, or sulfur is supplied

Use and benefits

MOP is the dominant potassium source worldwide because of its high analysis and comparatively low cost per unit of potassium, and it is used across a broad range of field crops where chloride sensitivity is not a limiting concern.

  • Lowest cost per unit of potassium among common potassium fertilizers
  • High analysis reduces bulk and transport cost
  • Suitable for most field crops that are not notably chloride-sensitive

Application principles

General practice weighs MOP against chloride-sensitive alternatives such as sulfate of potash for crops where quality or chloride tolerance is a concern, and considers soil potassium status and cation exchange capacity, which influence how well potassium is retained against leaching.

Environmental considerations

Potassium is retained relatively well by soils with adequate cation exchange capacity, but on coarse-textured or low-exchange-capacity soils it can be more prone to leaching. Repeated heavy use of chloride-containing fertilizers can also contribute to localised soil salinity concerns in some conditions.

Relationships

Evidence-backed connections in the knowledge graph.

Scope & limitations

Geographic scope: Global overview of muriate of potash as the dominant potassium fertilizer. Suitability relative to chloride-sensitive crops and soils varies by cropping system and region.

Climate context: Potassium leaching risk is greatest on coarse-textured, low-cation-exchange-capacity soils under high rainfall or irrigation.

  • This entry describes composition and general behaviour; it is not a potassium rate recommendation.
  • Chloride sensitivity varies widely among crops and should be confirmed against crop-specific agronomic guidance before choosing between MOP and chloride-free potassium sources.
  • Soil salinity and leaching risk depend on local soil, irrigation water quality, and climate, which are not detailed here.

Sources

This article draws on the following authoritative sources. See our sources & methodology for how they are selected.

  1. [1]FAO — Food and Agriculture Organization (opens in a new tab)

    Food and Agriculture Organization of the United Nations (FAO)

    Authoritative

    Cited for: Potassium fertilizer sources and global use

    Type:
    Intergovernmental organization
    Jurisdiction:
    Global
    Accessed:
    2026-07-12
  2. [2]IFA — International Fertilizer Association (opens in a new tab)

    International Fertilizer Association (IFA)

    Moderate

    Cited for: Muriate of potash product characteristics

    Type:
    Standards body
    Jurisdiction:
    Global
    Accessed:
    2026-07-12
  3. [3]USDA NRCS — Natural Resources Conservation Service (opens in a new tab)

    USDA Natural Resources Conservation Service (NRCS)

    Authoritative

    Cited for: Potassium behaviour and soil retention

    Type:
    Government agency
    Jurisdiction:
    United States
    Accessed:
    2026-07-12
  4. [4]AHDB — Agriculture and Horticulture Development Board (opens in a new tab)

    Agriculture and Horticulture Development Board (AHDB)

    High

    Cited for: Potassium management context

    Type:
    Government agency
    Jurisdiction:
    United Kingdom
    Accessed:
    2026-07-12